Structure and dynamics of dense colloidal ellipsoids at the nearest-neighbor length scale

Summary, in English

Anisotropic particles are known to exhibit a richer and more complex phase behavior in comparison to their spherical counterpart. While the majority of the existing studies address structural properties, the dynamic behavior of anisotropic particles is a relatively lesser explored avenue. Using multispeckle ultra-small-angle x-ray photon correlation spectroscopy (USA-XPCS), we have carried out a systematic investigation of the structural and dynamic properties of colloidal ellipsoids at the nearest-neighbor length scale. The USA-XPCS measurements have allowed us to probe, as a function of the volume fraction, the q-dependent effective structure factor, Seff(q), along with the effective long time diffusion coefficient, Deff(q), for this anisotropic system. Our results indicate a scaling behavior of Deff(q) with 1/Seff(q) from which we have estimated the effective amplitude function Aeff(q), which can be directly related to the effective hydrodynamic function Heff(q). Aeff(q) shows a similar q dependence to that of S(q). Our investigation also allows for the precise determination of the volume fraction corresponding to the arrest transition.

• Author: Antara Pal; Md Arif Kamal; Peter Holmqvist; Peter Schurtenberger
• Department/s: Physical Chemistry
• Publishing year: 2021-06
• Language: English
• Publication/Series: Physical Review Research
• Volume: 3
• Issue: 2
• Links: http://dx.doi.org/10.1103/PhysRevResearch.3.023254
• Document type: Journal article
• Publisher: American Physical Society
• Topic: Physical Chemistry (including Surface- and Colloid Chemistry)
• Status: Published
• ISBN/ISSN/Other: ISSN: 2643-1564